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1.
J Environ Manage ; 354: 120428, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38387359

RESUMO

Utilising cardboard waste for the partial substitution of cement within concrete has the potential to yield significant sustainability benefits. Cardboard waste is abundantly available, and a significant proportion of this material is disposed of in landfill. However, conversion of waste cardboard into kraft fibres (KFs) for concrete implementation can be utilised in the building and construction industry. Therefore, identification of sustainability variables associated with cardboard waste in concrete is vital. In this study, two KF composites satisfied the criteria for low stress grade concrete and were subsequently evaluated. SFKF5 mix design contained 5% KFs and SFKF105 contained 10% KFs with 5% metakaolin (MK). Both composites had silica fume (SF) as a fibre modification technique for durability purposes. A life cycle assessment (LCA) determined the environmental effect of waste cardboard integration. A Monte-Carlo simulation was utilised as the sensitivity analysis to investigate transportation and energy manufacturing greenhouse gas (GHG) emission variables. LCA results of SFKF105 had a savings of 11%, 8%, 4% and 1% for terrestrial acidification potential, global warming potential (GWP), terrestrial ecotoxicity potential (TEP) and human toxicity potential, respectively. SFKF5 revealed savings of 3%, 2% and 4% for GWP, TEP and marine eutrophication potential, respectively. The additional travel requirements of KFs and MK to the cement batching plant for composite production did not surpass the embodied energy and travel emissions of the control. However, this was negated due to the additional energy requirements to manufacture KFs. The control, SFKF5, and SFKF105 had an average total of 572, 1023 and 997 kgCO2-eq/m3, respectively.


Assuntos
Indústria da Construção , Gases de Efeito Estufa , Humanos , Animais , Aquecimento Global , Gases , Estágios do Ciclo de Vida
2.
Materials (Basel) ; 15(24)2022 Dec 15.
Artigo em Inglês | MEDLINE | ID: mdl-36556769

RESUMO

The building and construction industry consumes a significant amount of virgin resources and minimizing the demand with alternative waste materials can provide a contemporary solution. In this study, thermal components of kraft fibres (KFs) derived from waste cardboard are investigated. The mechanical properties containing KFs within concrete composites are evaluated. Metakaolin (MK) and KFs were integrated into concrete samples as a partial substitute for cement. Silica Fume (SF) was applied to the KF (SFKFs) with a view to enhancing the fibre durability. The results indicated that there was a reduction in compressive strength of 44 and 56% when 10% raw and modified KFs were integrated, respectively. Raw, fibre and matrix-modified samples demonstrated a 35, 4 and 24% flexural strength reduction, respectively; however, the tensile strength improved by 8% when the matrix was modified using MK and SFKF. The morphology of the fibres was illustrated using a scanning electron microscope (SEM), with an energy dispersion X-ray spectroscopy (EDS) provision and Fourier transform infrared spectroscopy (FT-IR) employed to gain insights into their chemical nature. The thermal, calorimetric and combustion attributes of the fibres were measured using thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and pyrolysis combustion flow calorimetry (PCFC). SFKFs showed a lower heat release capacity (HRC), demonstrating a lower combustion propensity compared to raw KFs. Furthermore, the 45% decreased peak heat release rate (pHRR) of SFKFs highlighted the overall reduction in the fire hazards associated with these materials. TGA results also confirmed a lower mass weight loss of SFKFs at elevated temperatures, thus corroborating the results from the PCFC runs.

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